Published: Thickness Dependence of EO Properties in HZO Films: Evident Response down to 3 nm

Our paper entitled “Thickness Dependence of the Electro-optic Properties in Epitaxial Hf0.5Zr0.5O2 Thin Films: Evident Response Down to 3 nm” has been published in Appl. Phys. Lett. We found that although the effective EO coefficient, reff, remained almost unchanged down to 10 nm and decreased with a further decrease in thickness, the evident EO response was observed down to 3 nm, which agrees with the fact that HZO films can maintain ferroelectric properties down to a few monolayers in thickness. The small reff in the HZO films with thickness below 5 nm is attributed to the stabilization of the ferroelectric rhombohedral-like phase.

Published: Distinct roles of Mg and Li in affecting EO properties of ZnO thin films

Our paper entitled “Distinct Roles of Mg and Li in Affecting the Electro-optic Properties of Wurtzite ZnO Thin Films” has been published in Appl. Phys. Lett. Increasing the Mg content in ZnO significantly enhances internal parameter u and reduces the anion–cation bond lengths along the c-axis direction. This facilitates Zn displacement along the c-axis direction and increases electric susceptibility, enhancing the ionic contribution to rc. As opposite to Mg, Li incorporation produces slight lattice expansion and increases anion–cation bond lengths along the c-axis orientation. Larger rc could be reached by optimizing the Mg and Li content as well as the thickness. These findings suggest the great potential of widegap ZnMgO:Li thin films for applications to EO modulation in ultraviolet band.

Seminar: Prof. Jong Eun Ryu

On April 30, Prof. Jong Eun Ryu (North Carolina State University) visited us and lectured on XPCS study of ferroelectric materials.

Lecturer: Prof. Jong Eun Ryu (North Carolina State University)
Investigating Domain Dynamics in Ferroelectric Materials Using In-Situ X-Ray Photon Correlation Spectroscopy

Staff member

Dr. Shinya KONDO (assistant professor) and Dr. Kosuke ONO (research assistant professor) join us today.

Dr. Xueyou YUAN was promoted to a research lecturer. Congrats!

Published: Dynamic Domain Motion Enhancing Electro-optic Performance in Ferroelectric Films

Our paper entitled “Dynamic Domain Motion Enhancing Electro-optic Performance in Ferroelectric Films” has been published in Appl. Phys. Lett. We found that rhombohedral (111)/(11-1)-PZT film, consisting of domains with two distinct out-of-plane polarization components, exhibited an enhanced EO response upon the application of an AC field of approximately 40 kV/cm. This enhanced EO response was directly related to field-induced reversible domain switching, as confirmed by electrical measurements and time-resolved synchrotron XRD. These results indicate that the dynamic domain motion in ferroelectrics is an effective strategy for enhancing the EO response.

2026 Energy Func. Mater. Eng. Lab., Nagoya Univ. [Internal link]